What is used in the preparation of calcium sulphate hemihydrate? 

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RRB Technician Grade III Official Paper (Held On: 29 Dec, 2024 Shift 2)
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  1. Sodium Carbonate  
  2. Gypsum 
  3. Copper Sulphate 
  4. Sodium Hydrogen Carbonate 

Answer (Detailed Solution Below)

Option 2 : Gypsum 
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The correct answer is Gypsum.

Key Points

  • Gypsum (CaSO4·2H2O) is used in the preparation of calcium sulphate hemihydrate (CaSO4·0.5H2O).
  • Calcium sulphate hemihydrate is commonly known as Plaster of Paris.
  • The process involves heating gypsum to around 150°C to 180°C, which partially dehydrates it.
  • Plaster of Paris is widely used in construction, sculpture, and medical applications for making casts and molds.

Additional Information

  • Gypsum:
    • It is a soft sulfate mineral composed of calcium sulfate dihydrate.
    • Gypsum is naturally occurring and is mined from sedimentary deposits.
    • It is used in various industries, including agriculture as a soil conditioner and in the production of cement.
  • Plaster of Paris:
    • It is a quick-setting gypsum plaster consisting of a fine white powder (calcium sulfate hemihydrate).
    • When mixed with water, it rehydrates and sets quickly, making it useful for casting molds and medical bandages.
  • Dehydration Process:
    • The heating of gypsum to produce Plaster of Paris is a controlled process to ensure partial dehydration.
    • Overheating can lead to complete dehydration, forming anhydrite (CaSO4), which has different properties.
  • Uses of Plaster of Paris:
    • In construction, it is used for making decorative elements and false ceilings.
    • In orthopedics, it is used for making casts for broken limbs.
    • In art, it is used for making sculptures and other decorative items.
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