In which year did Langmuir reform the Lewis concept by abandoning the idea of a stable cubical arrangement of the octet and introducing the term ‘covalent bond’?

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SSC CGL 2022 Tier-I Official Paper (Held On : 05 Dec 2022 Shift 3)
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  1. 1919
  2. 1915
  3. 1921
  4. 1917

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Option 1 : 1919
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Detailed Solution

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The correct answer is 1919.

Key Points

  • Langmuir in 1919 refined the Lewis postulation by abandoning the idea of the stationary cubical arrangement of the octet, and by introducing the team covalent bond.
  • Covalent bonds;-
    • They are formed by the sharing of electrons between two atoms so that both can achieve a filled outermost shell.
    • When two atoms share one electron pair they are said to be joined by a single covalent bond.
  • In many compounds, we have multiple bonds between atoms. The formation of multiple bonds envisages the sharing of more than one electron pair between two atoms.
  • If two atoms share two pairs of electrons, the covalent bond between them is called a double bond.
  • When combining atoms share three electrons Paris as in the case of two nitrogen atoms in the Nmolecule and the two carbon atoms in the ethyne molecule, a triple bond is formed.

Additional Information

  • The first description of covalent bonding was provided by Gilbert N. Lewis in terms of the sharing of electron pairs between atoms
  • He related the process to the attainment of noble gas configurations by reacting atoms as a result of sharing of electrons.
  • Kossel and Lewis in 1916 developed a theory of chemical combination between atoms known as the electronic theory of chemical bonding.
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