How many anions surround a sodium ion in a crystal lattice of sodium chloride?

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SSC CGL 2022 Tier-I Official Paper (Held On : 06 Dec 2022 Shift 3)
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  1. Six
  2. Eight
  3. Seven
  4. Nine

Answer (Detailed Solution Below)

Option 1 : Six
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Detailed Solution

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The correct answer is Six.Key Points

  • Cations and anions are combined to form ionic molecules. \
  • In sodium chloride, the cation is sodium (Na+) and the anion is chloride (Cl-).
  • The anion (Cl-) and the cation (Na+) in the crystal structure alternate back and forth in a predictable pattern.
  • The cubic lattice of sodium ions and a related cubic lattice of chlorine ions are entangled in the crystal structure of sodium chloride.
  • Thirteen sodium ions and fourteen chloride ions make up each unit cell of sodium chloride.
  • Eight unit cells share an ion at a corner, two unit cells share one at the face's center, and four unit cells share one at the edge.
  • Each sodium ion is surrounded by six chloride ions, and each chloride ion is surrounded by six sodium ions.
  • The sodium chloride unit cell contains four sodium ions and four chloride ions.

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Additional Information

  • The symmetrical three-dimensional structural groupings of atoms, ions, or molecules inside a crystalline solid as points are known as the crystal lattice.
  • It can be characterized as the spatial geometrical arrangement of the atoms, ions, or molecules that make up the crystalline solid.
  • A crystal lattice is created by substituting a representative point for each group of atoms. 
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