What is the oxidation number of chromium in potassium dichromate? 

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. +2
  2. +3
  3. +6
  4. +12

Answer (Detailed Solution Below)

Option 3 : +6
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Detailed Solution

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CONCEPT:

Oxidation Number:

  • The oxidation number of an element in a compound is the charge it would have if all bonds were ionic.
  • For polyatomic ions, the sum of the oxidation numbers of all atoms equals the charge of the ion.
  • Potassium dichromate (K2Cr2O7) contains chromium in a compound where its oxidation number can be determined using the rules for calculating oxidation numbers.

EXPLANATION:

  • In potassium dichromate, the formula is K2Cr2O7.
  • Potassium (K) has an oxidation number of +1.
  • Oxygen (O) has an oxidation number of -2.
  • Let the oxidation number of chromium (Cr) be x.
  • Using the rule that the sum of oxidation numbers equals the total charge of the compound (which is 0 for neutral compounds):
    • 2(+1) + 2x + 7(-2) = 0
    • 2 + 2x - 14 = 0
    • 2x - 12 = 0
    • 2x = 12
    • x = +6

Therefore, the oxidation number of chromium in potassium dichromate is +6.

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