The temperature at which the molar specific volumes for liquid and vapor phases become equal is termed as:

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  1. Boiling point
  2. Critical temperature
  3. Triple point
  4. Temperature of vaporization

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Option 2 : Critical temperature
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Concept:

It is the point at which the slope changes from positive to negative and at this point the slope is zero.

 

F1 S.C Madhu 08.05.20 D12

 

  • It represents the highest pressure and temperature at which the liquid and vapor phases coexist in equilibrium.
  • All the thermodynamic properties of liquid and vapor phases are identical at the critical point.
  • The critical point is the point at which the liquid and vapor phases are not distinguishable, hence molar specific volumes for liquid and vapor phases will be equal.
  • The temperature pressure and volume at the critical point are called critical temperature Tc , critical pressure Pc, and critical volume Vc
  • It is a fixed point that’s why the degree of freedom will be zero.
  • Dryness fraction (x) is not defined at the critical point.

 

Note:

The critical point properties of water are

Pc = 221.2 bar

Tc = 374.15° C

Vc = 0.00317 m3/kg

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