The ratio of specific rate constants at two different temperatures, separated by 10 °C, is called as: 

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. Activity coefficient 
  2. Activation energy
  3. Threshold energy 
  4. Temperature coefficient 

Answer (Detailed Solution Below)

Option 4 : Temperature coefficient 
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CONCEPT:

Temperature Coefficient

  • The temperature coefficient is the ratio of specific rate constants (k) at two different temperatures separated by 10°C.
  • This is a measure of how the rate of a chemical reaction changes with temperature.
  • It is based on the principle that reaction rates generally increase with temperature due to increased molecular collisions and the energy required to overcome the activation barrier.
  • Mathematically, the temperature coefficient is expressed as:

    Temperature Coefficient = k2/k1

    Where k2 and k1 are the rate constants at two temperatures separated by 10°C.

EXPLANATION:

  • The ratio of specific rate constants at two different temperatures is not related to activity coefficient, activation energy, or threshold energy.
  • Activity coefficient measures the effective concentration of a species in a solution and is unrelated to temperature changes.
  • Activation energy refers to the minimum energy required to start a reaction, while threshold energy is the minimum energy required for molecular collisions to result in a reaction.
  • The specific term "temperature coefficient" directly relates to the change in reaction rate constants with temperature, making it the correct answer.

Therefore, the correct answer is option 4: Temperature Coefficient.

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