The major product formed in the following reaction is
F2 Vinanti Teaching 21.11.23 D1

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CSIR-UGC (NET) Chemical Science: Held on (18 Sept 2022)
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  1. F4 Vinanti Teaching 05.09.23 D43
  2. F4 Vinanti Teaching 05.09.23 D44
  3. F4 Vinanti Teaching 05.09.23 D45
  4. F4 Vinanti Teaching 05.09.23 D46

Answer (Detailed Solution Below)

Option 4 : F4 Vinanti Teaching 05.09.23 D46
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Detailed Solution

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Explanation:-

  • The reaction pathway is shown below:

F2 Vinanti Teaching 21.11.23 D2

  • In the first step of the reaction, it is shown that the reaction of Ac2O with Lewis acid BF3 forms a carbocation (CH3CO+) which reacts to form an intermediate product.

F2 Vinanti Teaching 21.11.23 D3

F2 Vinanti Teaching 21.11.23 D4

  • In the next step of the reaction, the intermediate product undergoes a cyclization reaction through the release of a molecule of H2O followed by a [4+2] cycloaddition and decarboxylation reaction to give the final product.

F2 Vinanti Teaching 21.11.23 D5

Conclusion:-

Hence, the major product formed in the following reaction is 
F4 Vinanti Teaching 05.09.23 D46

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