The formation of Fe2O3(s), SO2(g) and SO3(g) by heating ferrous sulphate is an example of:

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AAI Junior Assistant (Fire Service) Official Paper (Held On: 21 Apr, 2025 Shift 1)
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  1. cecomposition reaction
  2. displacement reaction
  3. combination reaction 
  4. redox reaction

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Option 1 : cecomposition reaction
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The correct answer is decomposition reaction.

Key Points

  • A decomposition reaction involves the breakdown of a single compound into two or more simpler substances.
  • When ferrous sulfate (FeSO₄) is heated, it decomposes into ferric oxide (Fe₂O₃), sulfur dioxide (SO₂), and sulfur trioxide (SO₃).
  • The chemical equation for this reaction is: 2FeSO₄ → Fe₂O₃ + SO₂ + SO₃.
  • This reaction is an example of a thermal decomposition reaction, as it requires heat to occur.
  • The thermal decomposition of ferrous sulfate is commonly observed in laboratory experiments to demonstrate the concept of decomposition reactions.

Additional Information

  • Decomposition Reaction:
    • It is a type of chemical reaction in which a single compound breaks down into two or more simpler substances.
    • Decomposition reactions are often classified based on the energy source, such as thermal decomposition (heat), electrolytic decomposition (electricity), or photolytic decomposition (light).
  • Thermal Decomposition:
    • This involves breaking down compounds using heat.
    • Examples include the decomposition of calcium carbonate (CaCO₃ → CaO + CO₂) and ferrous sulfate (2FeSO₄ → Fe₂O₃ + SO₂ + SO₃).
  • Redox Aspect:
    • While this reaction involves decomposition, it also has redox characteristics, as iron is oxidized and sulfur is reduced during the process.
    • This dual nature is common in certain decomposition reactions.
  • Applications of Decomposition Reactions:
    • Used in industries for extracting metals from their ores.
    • Helps in the production of gases like oxygen and carbon dioxide in laboratories.
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