The resonance hybrid structure of benzene indicates _______ geometry. 

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. tetrahedral 
  2. hexagonal 
  3. pentagonal 
  4. heptagonal

Answer (Detailed Solution Below)

Option 2 : hexagonal 
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CONCEPT:

Resonance Hybrid Structure and Geometry of Benzene

  • Benzene is an aromatic compound with the molecular formula C6H6.
  • The resonance hybrid of benzene is a combination of two equivalent resonance structures, which depict alternating single and double bonds in the ring.
  • Instead of discrete single and double bonds, the resonance hybrid indicates that all six carbon-carbon bonds in benzene are equivalent and intermediate in length between single and double bonds.
  • This delocalization of π-electrons results in a symmetrical structure with equal bond lengths.

EXPLANATION:
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  • The resonance hybrid structure of benzene forms a planar, cyclic arrangement of six carbon atoms.
  • Each carbon atom is sp2-hybridized, resulting in 120° bond angles, which ensures the structure is perfectly planar.
  • The six carbon atoms form a regular hexagonal geometry, where the delocalized π-electrons above and below the plane contribute to the stability of benzene.
  • This hexagonal geometry is a key feature of benzene's resonance hybrid structure.

Therefore, the resonance hybrid structure of benzene indicates hexagonal geometry, and the correct answer is Option 2.

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