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ANTI MARKOVNIKOV RULE:
Addition of halo acid or protic acid to an alkene in presence of peroxide in such a way that proton makes a bond with most substituted carbon atom of alkene or in simple words proton will form a bond with carbon which has less no. of hydrogens and nucleophile will form a bond with carbon which has more no. of hydrogens.
Mechanism: Peroxide effect proceeds via the free radical chain mechanism
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Last updated on Jun 16, 2025
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