The expected H-H-H bond angle in [H3]+ is -

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HPSC Assistant Professor 2018 Chemistry (Official Paper)
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  1. 60°
  2. 90°
  3. 120°
  4. 180°

Answer (Detailed Solution Below)

Option 1 : 60°
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Detailed Solution

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CONCEPT:

Molecular Geometry and Bond Angles

  • The bond angle in a molecule is determined by the geometry of the molecule, which depends on the number of bonding pairs and lone pairs of electrons around the central atom.
  • For the species \([H_3]^+\), the molecular geometry can be understood by considering the electron pairs around the central atom.
  • \([H_3]^+\) (protonated hydrogen) is an example of a molecule with a triangular or cyclic structure.

EXPLANATION:

F1 Priya Teaching 5 11 2024 D15

  • \([H_3]^+\) has a triangular structure where three hydrogen atoms are symmetrically arranged around a central hydrogen atom.
  • In a perfect equilateral triangle, the bond angles are 60°, which is the expected H-H-H bond angle in \([H_3]^+\).
  • This triangular arrangement minimizes repulsion between the bonding pairs of electrons.

CONCLUSION:

The correct answer is 60°.

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